• OK, so what we have to do is get back underneath this reaction, and see what the molar quantities are.

    我们应该做的是,再回到这个反应,看看摩尔是多少。

    麻省理工公开课 - 固态化学导论课程节选

  • However, the thing to remember is, when you look at heats of reaction under those conditions it's all well and good.

    相反,需要记住,当你需要知道反应中放出的热时,这些是很有用的。

    麻省理工公开课 - 热力学与动力学课程节选

  • But, the reaction says I need twice as much mag as tickle if this reaction is going to go to completion.

    但是这个反应告诉我们,镁的应该是四氯化钛的两倍,如果要反应完全的话。

    麻省理工公开课 - 固态化学导论课程节选

  • So what we'll end up with is boron plus, 1 s 2 2 s 2 1 s 2, 2 s 2, E and what we say is the delta energy or the change in energy as the same thing as saying the energy of the products minus the energy of our reactant here, that's how much energy we have to put into the system to eject an electron.

    所以结果应该是正一价的硼,电子排布为,我们说,Δ,也就是,E,的变化,等于生成物的能,减去反应物的能,这就是我们从这个系统中,打出一个电子所需要的能

    麻省理工公开课 - 化学原理课程节选

  • OK, so this, what I've sketched here would be a constant pressure calorimeter. There's a reaction.

    好,我画的就是一个恒压热计,其中进行一个反应

    麻省理工公开课 - 热力学与动力学课程节选

  • So delta u of reaction is approximately equal T to negative Cv for the calorimeter times delta T.

    所以反应的ΔU近似等于,负的热计的Cv乘以Δ

    麻省理工公开课 - 热力学与动力学课程节选

  • Normally this is used for a reaction in the condensed phases and liquid usually.

    通常它是用于凝聚态,液体相的反应,这是一个恒压热计。

    麻省理工公开课 - 热力学与动力学课程节选

  • Anybody have an idea? What's the one function of state? I'm the system, the rest are the surrounding. What's the one function of state that's constant when I'm doing all my chemical reactions to move my arms around?

    态函数又是什么呢?,我是一个系统,其余的是周围的环境,那么当我在做所有的化学反应,去四处移动我的手臂的时候,什么是常数?

    麻省理工公开课 - 热力学与动力学课程节选

  • I've got reactants and calorimeter at T1.

    我有T1下的反应物和热计。

    麻省理工公开课 - 热力学与动力学课程节选

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