• He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.

    他提到离子百分数,是指中,并非个分子中。

    麻省理工公开课 - 固态化学导论课程节选

  • So we started with 10 valence electrons, we used up 8 of those electrons in terms of making bonds.

    我们开始有十个价电子,然后用掉了八个电子来成

    麻省理工公开课 - 化学原理课程节选

  • Well, if this bond has completely identically equal sharing of electrons, then this bond will be nonpolar.

    如果连的两个原子,对上的电子吸引程度是完全等价的,那么这根是非极性的。

    麻省理工公开课 - 固态化学导论课程节选

  • A TSV file, tab-separated values uses the same thing but a tab character, if you wanna output an actual tab character, the result of hitting the tab key, \t you do use backslash T. That's so those kinds of files are made.

    而TSV文件,“制表符分隔“文件,顾名思义,就是用制表符来分隔每列,如果你想输出个真正的制表符,点击tab,你也可以用,这就是那些文件的形成方式。

    哈佛公开课 - 计算机科学课程节选

  • So we can have four total hydrogens bonding here, - and we can think about how to describe these carbon- carbon bonds.

    我们这里共有四个氢原子成,我们可以考虑怎么来-,描述碳碳

    麻省理工公开课 - 化学原理课程节选

  • So let's see, we started with 8 bonding electrons, and we used up only 4, so the answer is yes, we have 4 bonding electrons left.

    那么让我们来看看,我们开始有八个成电子,然后只用掉了四个,因此答案应该是还有剩余,我们还剩下了四个成电子。

    麻省理工公开课 - 化学原理课程节选

  • We only have the one bond so the actual HF molecule is polar, it has a net dipole.

    但HF中只有,所以分子也是极性的而甲烷中有个网状偶极。

    麻省理工公开课 - 固态化学导论课程节选

  • The other thing is that we can re-write our h c n in terms of bonds.

    还有件事是我们可以用的形式来表示氰化氢。

    麻省理工公开课 - 化学原理课程节选

  • So if we go ahead and name this bond, what we're going to name it is sigma, - because that's the -- basically the shape of the bond or that's how our bond is coming together.

    所以如果我们继续并且命名这一键,就是我们要命名的这个,因为这是-,基本上的形状,或者这就是是怎么到起的。

    麻省理工公开课 - 化学原理课程节选

  • So let's think about methane using valence bond theory.

    让我们用价电子成理论来看看甲烷。

    麻省理工公开课 - 化学原理课程节选

  • so you can see that there is going to be two sets in antibonding, three sets in bonding for a net of one, giving us the single bond.

    因此你能看到,反轨道上有两组,三组成,得到组净成,所以成的是单

    麻省理工公开课 - 固态化学导论课程节选

  • And so both of these lobes together constitute a pi bond.

    上下两片叶起组成了根π

    麻省理工公开课 - 固态化学导论课程节选

  • And ultimately we are going to get to this state where we are going to form a bond.

    最终我们将得到这个状态,即形成

    麻省理工公开课 - 固态化学导论课程节选

  • I formed a bond, an ionic bond.

    生成了,离子

    麻省理工公开课 - 固态化学导论课程节选

  • And, 435KJ/mol we can come up with a number of 435 kilojoules per mole HF Well, if we want to get HF, let's see what the FF bond is.

    并且,我们想到个数,如果我们想得到,我们看看FF是什么。

    麻省理工公开课 - 固态化学导论课程节选

  • However, on Friday we will use a different approach so we can talkabout bonding within atoms that have more than two atoms, molecules with more than two atoms.

    但是,在周五我们,会用种新的办法来讨论,不止两个原子的分子的成

    麻省理工公开课 - 化学原理课程节选

  • So let's take the case of acetylene where we have two carbon atoms that are going to be triple bonded to each other, each are bonded to a carbon and then to one hydrogen.

    让我们来看看乙炔的例子,我们有两个碳原子,成三,每个碳和个碳个氢相连。

    麻省理工公开课 - 化学原理课程节选

  • And then we end up having 6 shared electrons, 2 from each of the bonds, so we end up with a formal charge on sulfur of plus 1.

    然后我们有六个共用电子,每个两个,因此最终硫的形式电荷量为正

    麻省理工公开课 - 化学原理课程节选

  • So, another way to talk about dissociation energy is simply to call it bond strength, it's the same thing, they're equal to each other.

    讨论离解能的另外种方式,是直接称它为的强度,它们是样的,彼此相等。

    麻省理工公开课 - 化学原理课程节选

  • So if you're trying to make a more complicated organic molecule carbon-carbon bonds are one of the most difficult things to make in organic chemistry, and it turns out that c n minus is a very reactive molecule, so it's a good way, even though we'll go over some drawbacks in a second, it is a good way to make carbon-carbon bonds.

    如果你要合成个更复杂的有机分子,碳碳是有机化学中,最难制造的,而实际上氰离子是种具有很高活性的分子,用它是个好办法,尽管我们会儿将看到它的些缺点,但它的确是个制造碳碳的好方法。

    麻省理工公开课 - 化学原理课程节选

  • But since in drawing Lewis structures actually, in some cases you do, you can draw a dotted line that means a 1 and 1/2 bond, but most in most cases, we just draw out both resonance structures, and the way that we say it's a resonance structure is that we put it in the brackets and we put an arrow between it.

    但是由于在画路易斯结构时,其实,在某些情况下是可以的,你可以画条虚线来表示又二分之一键,但是在多数情况下,我们就把两个结构都画出来,而我们说这是个共振结构的表示的方法是,把它们放在括号里,并在中间放个双箭头。

    麻省理工公开课 - 化学原理课程节选

  • So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.

    这就是苯环里的两种,我们还剩种,那就是这些p轨道之间,形成的双或者π,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个

    麻省理工公开课 - 化学原理课程节选

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