• So in terms of total numbers that we would need to complete our octets and fill our valence shells, we would need 18 electrons.

    因此要填满我们的“八隅体“,排满所有的壳层,我们总共需要十八个电子。

    麻省理工公开课 - 化学原理课程节选

  • So we could think about comparing the potassium ion to a sodium ion. They have the same charge of plus one.

    我们可以想象比较一下钾离子,与钠离子,它们都同样带有正一价的电荷。

    麻省理工公开课 - 化学原理课程节选

  • And you would expect that that would be a much stabler compound because, instead of plus one attracting plus one, now you have plus two attracting minus two.

    可以预见,这将会是更稳定的化合物,因为不再是一正离子吸引一负离子,而是二正离子吸引二负离子。

    麻省理工公开课 - 固态化学导论课程节选

  • And I was out there and the only place you could really get water, except for a few drinking fountains, were from the Evian booths and it talks on-- sand o three fifty for a bottle of water, which is pretty typical of these places, but what was interesting was the fact that this is shipped in from France.

    我也去看了,除了几个饮水机之外,唯一可以喝到水的地方,就是依云矿泉水的摊位,而它的一瓶水要3.5美元,这种地方通常都是这个,但有意思的是,这是由法国进口的

    耶鲁公开课 - 关于食物的心理学、生物学和政治学课程节选

  • The reason is because we already have a full valence shell for our hydrogen, it doesn't want any more electrons.

    原因是因为我们的氢,已经有一个排满的壳层了,它不再需要多余的电子了。

    麻省理工公开课 - 化学原理课程节选

  • So chlorine, if we talk about it in terms of electron affinity, we would be writing that we're actually gaining an electron here, and getting the ion, c l minus.

    那么,氯,如果我们要讨论它的电子亲和能,我们会假设它真的得到了,一个电子而变成离子,负一价的氯。

    麻省理工公开课 - 化学原理课程节选

  • Clearly, if I did nothing more, but I took every car, doubled its fuel economy, its emissions would go to 50% of what they are now, no other changes being made.

    显然,如果我什么也不做,但是我把没量车的汽油加倍,汽车废气排放量就会是现在的一半了,别的不会有什么改变。

    麻省理工公开课 - 固态化学导论课程节选

  • It's 109 . 5 is what we would expect for methane because it's tetravalent, but here we're just seeing something that's divalent, and they're both in p orbitals that are perpendicular to each other.

    因为甲烷是四价的,我们预测是109。,但这里我们,看到的是二价的,它们都在。

    麻省理工公开课 - 化学原理课程节选

  • Whereas for fluorine, fluorine is smaller than f minus is the one that's the outer shell shown here.

    而对于氟来说,氟原子更小,与外部壳层在这的负一氟离子相比。

    麻省理工公开课 - 化学原理课程节选

  • So, in other words, this c l minus is actually lower in energy than the reactants were.

    也就是说,负一氯离子,比原来的反应物的能量更低。

    麻省理工公开课 - 化学原理课程节选

  • - Then also, nitrogen, 3 minus -- these are all going to be isoelectronic with neon.

    然后还有,氮,负三-,这些都是与氖原子等电子的。

    麻省理工公开课 - 化学原理课程节选

  • So here we're talking about v plus 1, so if we were to write it just for the neutral electron itself, we would find that the electron configuration is argon, that's the filled shell in front of it.

    这里我们要分析的是正一价的钒离子,因此,我们先写出中性原子的电子排布,可以发现,其原子实是氩原子的电子排布,这些壳层已经被占满了。

    麻省理工公开课 - 化学原理课程节选

  • Our current portfolio has 11% allocated to domestic equities, 15% to foreign equities,and 4% to bonds, so traditional marketable securities account for 30% of assets.

    我们当前的投资组合中11%是国内股,15%是国外股,4%是债券,所以传统有证券占总资产的30%

    耶鲁公开课 - 金融市场课程节选

  • So the correct answer for titanium plus two Ar3d2 is going to be argon 3 d 2, whereas if we did not rearrange our order here 4s2 we might have been tempted to write as 4 s 2 so keep that in mind when you're doing the positive ions of corresponding atoms.

    所以正2钛离子,的正确答案是,然而如果我们不重新安排顺序,我们可能会写出2,所以请记住,它当你们在解关于原子,的正离子的时候。

    麻省理工公开课 - 化学原理课程节选

  • What about lithium 2+?

    那么二价的锂呢?

    麻省理工公开课 - 固态化学导论课程节选

  • If they awarded options that were "In the money" -that means already exercisable at profit -then they would be subject to a tax liability immediately, so they don't want to do that.

    如果这些奖励的股票期权是内期权,这说明期权行权即可赢利,这些利润是要交税的,当然他们想避免交税

    耶鲁公开课 - 金融市场课程节选

  • So 90% of your portfolio is in domestic marketable securities and only 10% is invested in things like real estate or venture capital or private equity -hardly enough to make a difference in terms of the portfolios returns.

    于是90%的投资都在本国有证券中,仅10%用于比如不动产,风险资本或私募股权投资,这一小块几乎对投资回报,没有什么作用

    耶鲁公开课 - 金融市场课程节选

  • So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.

    负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。

    麻省理工公开课 - 化学原理课程节选

  • So if we want to write out what that would be, it would just be to say that f minus is isoelectronic with neon.

    那么如果我们把它写出来,它应该就是负一价的氟离子与氖原子是等电子的。

    麻省理工公开课 - 化学原理课程节选

  • So this should immediately look like a problem because we know, in fact, that methane is tetravalent, and this is telling us it's only divalent.

    显然这看起来是一个问题,因为我们知道实际上,甲烷是四价的,而这告诉我们它仅仅是二价的

    麻省理工公开课 - 化学原理课程节选

  • So, we can say that -- if we have neon here and we want to think about what's isoelectronic, -- f minus would be isoelectronic. We also have oxygen -- what would the charge on oxygen be? Um-hmm, right. 2 minus.

    那么,我们可以说--如果我们这里有氖原子,而我们想知道与它等电子的是什么,负一价的氟离子就是与它等电子的,我们还有氧-,氧应该是几价的?没错,负二

    麻省理工公开课 - 化学原理课程节选

  • So, Lewis structures are really a model for a way to think about what the valence electron configuration is, and as I said, it's not based on quantum mechanics, it's something that Lewis observed far, far before quantum mechanics were discovered.

    路易斯结构实际上是一个用来考虑,电子排布的模型,而就像我说的,它并不以量子力学为基础,而是路易斯在以前发现的,在量子力学出现很早前。

    麻省理工公开课 - 化学原理课程节选

  • So, for example, if we think of the fluorine minus case, would you expect fluorine minus to be larger or smaller than neutral fluorine? Okay. I heard mostly larger, but a little bit of a mix in there, and it turns out that larger is correct.

    比如,如果我们来考虑一下负一价的氟离子的话,大家认为它大一些还是小一些?,对比于比中性氟原子,好的,我听到大部分人说大一些,但是也有一些不同意见,而正确答案应该是大一些。

    麻省理工公开课 - 化学原理课程节选

  • So, what we call this is the third ionization energy, or the negative of the binding energy, again of the 2 s orbital, but now it's in boron plus 2 to we're starting with.

    那么我们称它为第三电离能,或者负的束缚能,还是,2,s,轨道的,但现在我们是从正二硼离子开始的。

    麻省理工公开课 - 化学原理课程节选

  • So, in the case of boron plus 1, what we are starting with is the ion, so we're starting with a 2 s electron, 2 s 1 and then we're going to 2 s 1 here.

    在正一硼中,我们面对的是这个离子,本来就应该从,2,s,电子开始,然后这里变成。

    麻省理工公开课 - 化学原理课程节选

  • The highest occupied orbital is now the 2 s orbital, 1 s 2 2 s 1 so we're going to end up with boron 2 plus 1 s 2, 2 s 1, plus the electron coming out of there.

    现在最高的被占据轨道是,2,s,轨道,因此结果应该是正二价的硼,再加上一个出射的电子。

    麻省理工公开课 - 化学原理课程节选

  • And what I want to point out that we just figured out for molecular orbital theory, is that o 2 is a biradical, because remember, the definition of a radical is when we have an unpaired electron.

    我要指出的是,我们刚利用分子轨道理论,指导了O2是二自由基,因为记住,自由基的定义是,有个未配对的电子。

    麻省理工公开课 - 化学原理课程节选

  • This should make a lot of sense, because we know that a hydrogen has 1 s as it's outer-most or valence orbital, so it can be filled up just with two 1 s electrons.

    这也是很合理的,因为我们,知道氢只有,1,s,轨道,这就是它最外层的轨道或者说轨道,因此只要两个,1,s,电子就可以将它填满。

    麻省理工公开课 - 化学原理课程节选

  • We can write out what it is for any certain atom or ion x, X so it's just x plus an electron gives us x minus.

    我们可以用,X,来表示一个任意的原子或离子,因此可以写成,X,加一个电子等于负一价的

    麻省理工公开课 - 化学原理课程节选

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