So now if I look at my V1 over V2 to the gamma minus 1, that's T2 over T1.
于是把^=中2,的两个温度。
So, the first obvious one is to take V1 to V2 first with p constant. So take this path here.
从初态到末态可以有无数种路径2,甚至像这样,我们只研究两种。
We start at p1, V1. and p external is equal to zero.
从状态开始,外部压强为零。
V3 Here's the V4 over V3, V1 oops, sorry. V2 over V1, this is equal to the inverse of this.
所以就是这里的V4除以,哦,对不起,V2除以,它是它的倒数。
So this guy here gets rid of this, and I have my answer as V1 over V2 to =p2/p1 the gamma power is equal to p2 over p1.
这两项抵消掉了,于是等式,变成了^γ
p1 V1 Initial find -- there are many ways p2 V2 V1 I can get from one state to the other.
初态的氩气状态为,末态为。
There's p1 here, and p2 here So I'm starting at p1, V1. I'm starting right here And I'm going to end right here.
它的分子间作用力很小,十分接近理想气体,对它做一个压缩过程。
V2 So, if one goes to two and V1 goes to V2, and it's constant temperature, just what we've specified there.
如果状态1变到状态1并且体积从V1到,同时温度保持不变,这就是我们这里要讨论的问题。
V2/V1 There's a V1 over V2 here or V2 over V1.
这边是。
log So that's just the log of V2 over V1.
因此就是。
p1 V1 OK, so in my diagram now, I have p1, V1 for my gas.
于是可以画出现在的p-V图。
w=p1v1 So we write down p1, V1.
我们写下。
There is V1 here. There's V2 here.
比如说氩气。
OK, now we actually would like to simplify this or to write this in terms of not the volume change, v2/v1 but the pressure change. So, we have V2 over V1.
接下来我们将要把问题简化,不用体积变化来描述,而改作用压强变化来描述,现在我们有。
And if I draw a diagram on a T-V diagram of T-V V1 I'm starting with some V1 here.
画出过程的,图,what,I’m,doing,here,初态是。
v1=/p1 So V2 = /p2, and V1 = /p1.
因此v2=/p2,同样地。
v1 So we have p1, V1. We have stops.
内部气体压强为p1,体积为。
p2 There is going to be an internal pressure where T1 p1 is less than p2 and there's V1 and T1 here.
内部气体压强p1小于,体积为V1,温度为。
p1V1/R That p2 V2 over R, and then I have p1 V1 over R, the R's cancel out.
就是p2V2/R除以,两个R消掉了。
w This is just q plus w. There's w, RT1 ln q has to be R T1 log of V2 over V1.
而U等于q加,那是w,q应该是。
We can combine these two to see V2 that V4 over V1 must equal V3 over V2.
我们把这两个结合起来,得到V4除以V1等于V3除以。
I'm pressing on the gas. So I expect that to be a positive number. The pressure is constant 0 p. The V goes from V1 to zero.
我们对气体加压,所以这应该是一个正数,压强是常数,p,V从V1变成。
Remember it's the external pressure that's important. In this case, because it's a reversible process, the external pressure turns out to be always the same as the internal pressure.
是过程非常缓慢,比如我把体积,从V1压缩到V2时,我做得十分缓慢,在过程中的任何一点。
V1 This first integral is zero V1 to V1, then I get minus p2 times V2 minus V1 or p2 times V1 minus V2. Again, 0 a positive number.
先保持体积为,对pdV积分1,然后对p2dV从V1到V2积分,第一部分积分为。
/T We've got Cv integral from T1 to T2, dT over T is equal to minus R from V1 to V2 dV over V.
左边是Cv乘以,从T1到T2对dT积分。
So any point I pick on that path will be equal to p1, V1 to the gamma.
也就是说路径上面任取一个点,计算p,V^γ
v dv We have minus V1, V2, nRT over V dV.
负的v1,v2,nRT除以。
Let's take a system. Under constant pressure T1 V1, going to a second -- this is the system, so let me write the system here.
我们建立一个系统1,在恒定的压强T1,V1,下,变成了另一个系统,-这个初始的系统让我把它写在这。
So now let's try looking at something V2 where are V1 goes to V2.
现在我们考察一个过程,这个过程中系统的体积从V1变到。
p1 An isobaric process followed by V2 a constant volume process.
先保持压强为,体积从V1压缩到。
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