So, if I look at the mole ratios on the reaction over there I'm going to find that I'll be able to consume, at most, 1,029 over two, right?
所以,注意反应的摩尔比,我们会发现,1029摩尔的镁能被消耗,对吧?
This will be the definition of the mole as the amount of carbon weighing exactly 12 grams, so I would like to know now how many particles, how many carbons are there in that mole.
摩尔的定义就是,12克的碳的数量,我想知道有多少粒子,一摩尔会有多少碳粒子。
So, for example, for the chlorine case, we would say that the electron affinity for chlorine is actually positive 349 kilojoules per mole.
比如,以氯为例,我们可以说氯的电子亲和能,应该等于正的,349,千焦每摩尔。
The volumes per mole of that stuff.
每摩尔物质的体积。
What is the mole? Mole is a more practical value, something that we can handle tangibly.
什么是摩尔,它有实际值,我们可以很明白的掌握的。
The mole is something that was also defined in terms of carbon.
我们也以碳来,定义摩尔。
If you divide the two of them through you will get 6.02 times 10 to the plus 23 per mole.
如果你除以他们两个,你会得到6。02*10^摩尔。
So, what we get for the disassociation energy for a hydrogen atom is 424 kilojoules per mole.
因此,我们就得到了氢原子,离解能的大小为,424,千焦每摩尔。
60 If we look at 435 times 160, take the square root of that, we will end up with 264 kilojoules per mole, which sensibly lies between these two values.
35乘以,取平方根,我们会得到264千焦每摩,很合理地落在两数值之间。
So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.
如果我告诉大家单个氢原子的能量,是负的,1312,千焦每摩尔。
So this is not going to be a favorable process, we're going to find that the electron affinity is actually a negative 7 kilojoules per mole for nitrogen.
因此这并不是一个容易发生的过程,我们会发现氮的电子亲和能,应该是负的,7,千焦每摩尔。
So, if we took the case of nitrogen, if we add an electron to nitrogen and go to n minus, we find that the change in energy is 7 kilojoules per mole.
如果我们以氮为例,如果我们给氮增加个电子令它变成-1价的氮,我们会发现能量的变化是,7,千焦每摩尔。
I'm averaging it over the entire set of valence electrons which gives me 1.91 MJ per mole.
我是在整个价电子的集合上作平均,最后得到1。91兆焦每摩尔。
This means in order to do that we actually have to put 7 kilojoules per mole of energy into the reaction to make it happen.
这意味为了完成上面的反应,我们不得不往里面注入,7,千焦每摩尔的能量。
But when the concentration in the alloy is 50/50 by mole, something magical happens.
但是当合金中的浓度,是1比1的时候,有些神奇的事发生了。
And how do we get the value of the mole?
我们是如何得到摩尔的量值?
And, just to show some of the hidden balance here, 1 here we have one mole. I don't put a one in front.
这儿有一些隐藏的平衡,比如说这个1摩尔,我并没有在前面写了一个。
And the prefactor is 96.3 3 when you want to get a result in kilojoules per mole.
当使用千焦每摩表示键能3,时前因子为96。
Yeah, they're different but they are roughly on the order of about 1 MJ per mole.
是的,它们是不同的但它们大致上,都是一摩尔一兆焦耳。
Right? In other words I've got the stoichiometric coefficients in there and the values, and I'm subtracting the reactants from products -1652kJ/mol wind up with minus 1652 kilojoules per mole.
对吧?换句话说这里我用了化学,计量系数和生成热的值,从生成物中减去反应物,最后得到。
This is the number of carbons there is in a mole of carbon.
这是碳的数量,这是一摩尔的碳。
So I can make a quantity that I'll call V bar, which is the molar volume, the volume of one mole of a component in my system, and that becomes an intensive quantity.
所以我可以定义,一个叫做一横的量,这是摩尔体积系统中,一摩尔某种组分的体积,它就变成了。
So, let's compare this to the energy of the h 2 molecule, and we find that that's negative 3,048 kilojoules per mole.
那么,让我们将它与氢分子的能量比一比,我们发现氢分子的能量是负的,3048,千焦每摩尔。
And the change in energy for this reaction is negative 349 kilojoules per mole.
然后得到这个过程的能量变化为,负的,349,千焦每摩尔。
And, one other thing that I failed to point out, if you take a look at the energies associated with the outermost electrons, in this case, lithium, you see it's 0.5 megajoules per mole, and then what's the 6.26?
还有另外一点我忘记提到的是,如果你观察离最外层,的电子的能量,在这种情况,对于锂,你可以得到,它是每摩尔0。5兆焦,那么6。26是什么呢?
And, 435KJ/mol we can come up with a number of 435 kilojoules per mole HF Well, if we want to get HF, let's see what the FF bond is.
并且,我们想到一个数,如果我们想得到,我们看看FF键是什么。
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