There's no more 2 p orbitals to put it into, so we're going to actually have to double up.
现在并没有多余的2,p,轨道来放它,我们只能在其中一个,2,p,轨道上放上两个。
px And I arbitrarily chose to put it in the 2 p x, 2pz we also could have put it in the 2 p y or the 2 p z, it doesn't matter where you double up, they're all the same energy.
我任意地选择放入至,我们也可以把它放入2py或,它与你在哪双倍填充没有关系,它们都在相同的能级。
So, our two glitches we see when we go from the 2 p, or from 2 s to start filling the 2 p, and then we also get another glitch when we've half-filled the 2 p, and now we're adding and having to double up in one of those p orbitals.
因此,我们的看到的两个小偏差,一个是在开始进入,2,p,轨道,或者说在填满,2,s,轨道之后,开始填,2,p,轨道的时候出现的,另一个则是在,2,p,轨道半满之后,开始继续加电子,使得其中一个,p,轨道上的。
And now we get the p orbitals, remember we want to fill up 1 orbital at a time before we double up, so we'll put one in the 2 p x, then one in the 2 p z, and then one in the 2 p y.
我们到了p轨道,记住在双倍填充之前,我们想要每次填充至一个轨道,所以我们在2px填充一个然后2pz填充一个,然后2py填充一个。
So that's two of our types of bonds in benzene, and we have one type left, that's going to actually be the double bond or the pi bond that So we can have one bond here between this carbon's p orbital and this carbon's p orbital.
这就是苯环里的两种键,我们还剩一种,那就是这些p轨道之间,形成的双键或者π键,我们可以在这个碳的p轨道,和这个碳的p轨道之间有个键。
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