化学常用英语词汇_基础化学常用英语词汇 ... Electron Spin电子自旋 Atomic Orbital原子轨道 The s(p df)Orbital s(p,d,f)轨道 ...
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The graph to the left, this is the s orbital, symmetric.
在左边的图是对称的S轨道,对称的。
And yet, we know that the shape of the s orbital is spherical.
并且,我们知道S轨道是球状的。
If you compare the s orbital with the bottom lobe, these have a different sign so they're going to destructively interfere.
如果你们比较s轨道和下面这叶,它们正负号相反,所以它们相消干涉。
So, if I kind of circle where the probability gets somewhat substantial here, you can see we're much closer to the nucleus at the s orbital than we are for the p, then when we are for the d.
我把概率,很大的地方圈出来,你们可以看到在s轨道上,比p轨道更接近原子核,最远是d轨道。
So the most basic answer that doesn't explain why is just to say well, the s orbital is lower in energy than the p orbital, but we now have a more complete answer, so we can actually describe why that is.
所以最基本的答案是那没有解释,所以我们事实上可以描述,为什么是那样,但是我们现在有一个更复杂的答案,又是有效电荷量。
And yet, we know that the shape of the s orbital is spherical.
并且,我们知道S轨道是球状的。
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