• The graph to the left, this is the s orbital, symmetric.

    左边对称S轨道,对称的。

    youdao

  • And yet, we know that the shape of the s orbital is spherical.

    并且我们知道S轨道球状

    youdao

  • If you compare the s orbital with the bottom lobe, these have a different sign so they're going to destructively interfere.

    如果你们比较s轨道下面它们正负号相反,所以它们干涉

    youdao

  • So, what you find with the s orbital, and this is general for all s orbitals is that all of your nodes end up being radial nodes.

    对于s轨道你们会发现所有节点径向节点。

    youdao

  • For example, when we're talking about radial probability distributions, the most probable radius is closer into the nucleus than it is for the s orbital.

    举例来说我们讨论径向概率分布时,距离原子核可能半径s轨道半径,更的可以离原子核多近。

    youdao

  • So, if I kind of circle where the probability gets somewhat substantial here, you can see we're much closer to the nucleus at the s orbital than we are for the p, then when we are for the d.

    概率,很大地方圈出来,你们可以看到s轨道上,p轨道接近原子核最远是d轨道。

    youdao

  • So for example, if you look at the 1 s orbital here, you can see that actually it is lower in the case of the multi-electron atom than it is for the hydrogen atom.

    所以举例来说,如果看到这里1s轨道,你可以看到实际上多电子原子情况

    youdao

  • So for example, if you know how to draw an s orbital for a hydrogen atom, then you already know how to draw the shape of an s orbital or a p orbital for argon.

    个例子,如果你们知道如果,氢原子s轨道那么你们已经知道如何,画氩s轨道p轨道的形状

    youdao

  • So, our first orbital that an electron 1 s must be coming from is the 1 s.

    所以我们第一个肯定电子,被打出轨道

    youdao

  • This is the radial probability distribution formula for an s orbital, which is, of course, dealing with something that's spherically symmetrical.

    这个s轨道径向概率分布公式对于对称情形成立。

    youdao

  • And how many nodes do you see in the 3 s orbital?

    3s轨道多少个节点呢?

    youdao

  • So, for example, if we look at the 2 s orbital of argon, it's going to have the same amount of nodes and the same type of nodes that the 2 s orbital for hydrogen has.

    所以举例来说,如果我们2s轨道相同数量数,相同类型节点,对于的2s轨道。

    youdao

  • Let's consider again an s orbital for argon, so let's say we're looking at the 1 s orbital for argon.

    我们考虑一次s轨道所以我们我们1s轨道。

    youdao

  • So that's why we see the 2 p here, 1206 the 2 s is 12 06, and it makes sense that what we see as the greatest ionization energy, which is also the smallest kinetic energy is that 1 s orbital.

    就是为什么我们看到2p在这里,2,s对应,那么我们看到对应最高的电离能同时也对应最低动能的,应该就是1s轨道

    youdao

  • So what you see is actually a diminished lobe on the back part of this s p 3 orbital.

    你们看到,sp3轨道后面部分,有个小叶

    youdao

  • We talked about the wave function for a 2 s orbital, and also for a 3 s orbital.

    我们2s轨道函数讲过3s轨道。

    youdao

  • So that's the 1 s orbital - we have n squared or 1 degenerate orbitals.

    所以1s轨道,我们n平方,或者1个简并轨道

    youdao

  • So we can also look at this in terms of the 3 s orbital.

    我们可以同样来看3s轨道

    youdao

  • First of all, this is the two s orbitals in hydrogen, 1s plus 1s smearing to give us this sigma molecular orbital.

    首先氢气中的两个s轨道1s与1s轨道重叠,产生sigma分子轨道

    youdao

  • We said that's the 1 s orbital.

    我们1s轨道

    youdao

  • So, what we call this is the third ionization energy, or the negative of the binding energy, again of the 2 s orbital, but now it's in boron plus 2 to we're starting with.

    那么我们第三电离能或者束缚,还是,2s轨道现在我们是从价硼离子开始的。

    youdao

  • The space shuttle Columbia was the first space worthy shuttle in NASA 's orbital fleet.

    哥伦比亚号航空航天飞机美国航天局轨道船队第一有价值空间航天飞机。

    youdao

  • This has been an important motive behind China 's recent push to become a space power, with the launch of two manned orbital craft in 2003 and 2005.

    中国在2003年2005年成功发射载人飞船迅速成为宇航强国其重振动力

    youdao

  • So we expect to see two nodes right here in the 3 s orbital.

    所以3s轨道中我们预计看到两个节点

    youdao

  • The 1 s just comes from the fact that the molecular orbital is a combination of two 1 s atomic orbitals.

    是因为分子轨道两个,1s原子轨道组合

    youdao

  • So it's along the bond axis and it's between a carbon s p 2 hybrid, and then the hydrogen is just a 1 s orbital that we're combining here.

    所以沿着轴方向的,而且这里sp2杂化轨道一个1s轨道的结合,在这里我们可以合并他们。

    youdao

  • For example, for the 2 s, again what you see is that the multi-electron atom, its 2 s orbital is lower in energy than it is for the hydrogen.

    举例来说对于2s轨道,在多电子原子,可以看到的2s轨道能量低于氢原子

    youdao

  • In both cases we're taking an electron out of the 2 s orbital.

    这两种情况下我们拿走了一个2s,电子。

    youdao

  • And if we think about the six hydrogens, now each of those are going to bind by combining one of the carbon hybrid orbitals to a 1 s orbital of hydrogen.

    如果我们考虑六个氢原子每个会合起来化轨道成键,每个氢1s轨道

    youdao

  • So this is the 1 s star, sigma 1 s star orbital, and what you have in the center here is a node, right in the center between the two nuclei.

    1ssigma1s轨道中间这个节点,它两个原子核中间

    youdao

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