• If you looked at heteronuclear molecules and you wanted to compute the bond energy, you might start with the bond energies of the two constituents.

    如果你看那些相同电子的分子,你想计算共享能,你也许会从,两个组成部分的总能量。

    麻省理工公开课 - 固态化学导论课程节选

  • Because step five is that we need to fill in our bonding electrons, and we start it with filling in two electrons per bond.

    因为第五步要做的是将我们的成键电子填在这,所以我们开始在每个键处填上两个电子。

    麻省理工公开课 - 化学原理课程节选

  • With an indexed bond you don't have to do this calculation to get the real rate.

    对于物价指数债券,你无需,通过以上计算得到实际利率

    耶鲁公开课 - 金融市场课程节选

  • So what I want to tell you is we also always get the same bond order if we instead only deal with the valence electrons.

    我想要说的是我们如果,只考虑价电子也可以得到相同的键序。

    麻省理工公开课 - 化学原理课程节选

  • If you have a bond with an interest rate of 4.375% -that's not an easy one to divide by two but you would get half of that every six months until maturity.

    如果你持有一种利率为4.375%的债券,这个数除以2有点难算,而在债券到期前,每半年你能得到4.375%一半的券息

    耶鲁公开课 - 金融市场课程节选

  • So, using our simple valence bond theory, what we would expect is that we want to pair up any unpaired electrons in methane with unpaired electrons from hydrogen and form bonds.

    利用简单的价电子成键理论,我们预计,要把所有甲烷中没有配对的电子,和氢原子中没有配对的电子配对来形成键。

    麻省理工公开课 - 化学原理课程节选

  • So, we're going to start with talking about bonding, and any time we have a chemical bond, basically what we're talking about is having two atoms where the arrangement of their nuclei and their electrons are such that the bonded atoms results in a lower energythan for the separate atoms.

    那么,下面我们将从成键开始讲起,无论什么时候我们有一个化学键,基本上我们所讨论的,都是如何安排两个原子的原子核的位置,与电子的位置使得成键的两个原子,最终比分开时的能量更低。

    麻省理工公开课 - 化学原理课程节选

  • All right, so if we think about b h bond here, again, it's the sigma bond, and we're going to say it's a boron 2 s p 2 hybrid orbital interacting with a hydrogen 1 s orbital.

    这可以告诉我们,为什么它倾向于周围只有6个电子,好了,考虑一下这里的BH键,同样的,它是sigma键,我们说。

    麻省理工公开课 - 化学原理课程节选

  • So what I want to point out with this case in beryllium is that you don't have to use all of the electrons to figure out the bond order, and in fact, once you get to molecules 10 that are from atoms with atomic numbers of 8 or 10, you're not going to want to maybe draw out the full molecular orbital diagram.

    我要指出的是,在Be这种情况下,你不需要利用,所有的电子来指导键序,实际上,一旦分子中,原子序数到达了8或者,你也许不想画出,整个分子轨道图。

    麻省理工公开课 - 化学原理课程节选

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