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And it's for that whole unit that you've got some heat capacity. How much heat does it take the warm the entire thing up or the insides of the thing up by a degree? It's that number right.
由这个单位你能知道,一些热容的信息，要让这整个装置,或里面放置的东西,升温一度需要多少热量？
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And we had the similar statement by Kelvin about the heat engine that required that some heat gets dumped into a cold reservoir in the process of converting the heat from the hot reservoir into work.
相同的陈述,同样的有开尔文表述：,把热量完全从高温热源,转移至低温热源的过程中,必然有功的输出。
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The native structure is this double stranded structure here and if I heat it up slightly and I add some base, so under slightly basic conditions, these molecules will fall apart because you've created conditions where the hydrogen bonding is no longer favorable so they peel apart.
原始结构,在这里就是指DNA双链,如果我稍微加热,并且加入一些碱,在弱碱性的条件下,这些配对碱基会分开,这是因为在一定条件下,碱基对之间的氢键,不再稳定并且会断裂分开
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It's just how much heat is involved when we change the temperature. Now, the products have some heat capacity associated with them right, it takes a certain amount of heat if we make their temperature change, to either put it in or take it away, depending on which direction the temperature is changing.
问题就是当我们改变温度时,有多少热量发生了转移,生成物具有一定的热容,如果我们改变,它们的温度，就要输入或,提取一定的热量,这取决于温度改变的方向。
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But this is a compound, right, it has some non-zero heat of formation from the elements. So is water, right?
但这是种化合物，对吧？,它具有非零的生成热,水也是一样，对吧？
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So, you need some sort of property, something you can see, something you can measure, that tells you that heat has flowed.
所以，你需要某种性质，某种你能看到，能测量的东西，它会告诉你热量发生了流动。
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You can still calculate the heat that's released. This is what will tell you under some particular conditions what will actually happen. Where will you end up.
你仍然可以计算放热,在特定条件这些下这些物理量,能告诉我们将会发生的事情。
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You know the heat isn't going to flow from a cold body to a hot body without putting some work in to make that happen.
大家知道热量不会自发地,从冷的物理流动到热的物理,除非对它做功。
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There's no change in them, and then we also looked at some at non-state functions, work and heat, and saw that those aren't zero going around a cycle. Of course you can do work in a cyclic process, and heat can be exchanged with the environment at the same time.
它们不会有变化，然后我们研究了,一些非态函数，功和热量，并看到,沿着循环行进一周的话,它们并不是零，当然你可以在,一个循环过程中做功，而同时热量可以在系统,与外界环境之间进行交换。
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get back to the initial point is going to require some input from outside, like heat or extra work or extra heat or something because you've done an irreversible process.
如果要逆转它,回到初始点，就需要外界的投入，比如额外的功，额外的热量等等,因为你进行了一个不可逆过程。
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We're going to find other properties that do care about the history of the system like work, that you put in the system, or heat that you put in the system, or some other variables But you can't use those to define the equilibrium state.
我们还会发现其他一些,与系统的历史有关的性质,比如你对系统做的功，或者你向系统传递的热量，或其他的变量,但你不能用它们,来定义平衡态。
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Otherwise you're going to waste some of that heat somewhere along the way, some of energy.
否则你就必须在这个过程中,浪费一些热量。
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You couldn't just run something successfully in a cycle and get work out of it, using the heat from the hot reservoir, without also converting some of the heat that came in to heat that would flow into a cold reservoir.
如果一样东西在循环工作过程中,只有热从高温热源中流出，而没有热流入低温热源，那么此过程,不可能对外做功,不可能把所有热。
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It expands. You change your constraints on your system, you heat it up some more, then you take the heat source away, and you put it back in contact with the atmosphere. And you cool it a little bit, change the constraints, cool it a little bit more, and heat, and you've got a closed cycle engine.
让它与大气接触冷却,改变约束，使它继续冷却，然后又再次加热,这就是循环热机，我们以前也研究过，更复杂的机器。
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So we'd really like to be able to find some sort of equation of state, or some sort of rather function of state that's going to relate the heat going in or out of the system with that function of state, because this isn't going to do it.
所以我们真的想要去,找到一些态方程或者态函数,通过这个态函数可以表示热量,在系统与外界的交换,因为这个不能表示它。
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