在一定温度压力下,纯溶质B溶解在纯溶剂A中形成一定组分的溶液,其过程的焓变称为B的溶解焓,以符号△solH表示。
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还计算了体系的其它热力学性质,如溶解焓等。
Some thermodynamic properties, such as solution enthalpy, have been calculated.
氢气在液体中的摩尔溶解焓为正,摩尔溶解熵为负。
The molar enthalpy of solution was positive and the molar entropy was negative.
拟组分的热力学参数采用经验关系式来计算,其中对于正构烷烃的固-固转换焓、固固转换温度、熔解焓以及溶解温度,基于文献资料建立了新的关系式。
New correlations for solid-solid transition enthalpy, solid-solid transition temperature, fusion enthalpy and fusion temperature are also established in this work based on the data from literatures.
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