烷烃稳定性高,反应活性低,直接官能团化困难。
Paraffin has high stability, low reactivity, and it is difficult to give functional group to paraffin directly.
卤原子作为保护基,代替末端炔发生碳-氢官能团化反应。
Halogen atom could activate the triple bond and as the directing group, the triple bond occurs the electrophilic addition reaction.
以2 8篇文献综述了金属卟啉模拟酶催化氧化饱和碳原子官能团化的研究进展。
Studying development of functionalization of saturated carbon by catalytic oxidation wit metalloporphyrins as a mimic of the enzyme cytochrome P-450 was reviewed with 28 references.
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