Optimal conditions of azido reaction were obtained as follows: 2-amino-6-chloro-3,5- dinitropyridine 3.7g,acetone 50mL,sodium azide 1.7g,water 15mL, reacting at 20℃for 30min, the yield was 88.61%. Optimal conditions of thermolysis were obtained as follows:4,6-dinitro-7- aminotetrazolo1,5-apyridine 1.
叠氮化反应最佳实验条件为2-氨基-6-氯-3,5-二硝基吡啶3.7g,丙酮50mL,叠氮化钠1.7g,水15mL,20℃反应30min,收率为88.61%。
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研究了叠氮化铅晶体的热分解和爆炸过程。
The thermal decomposition and detonation of lead azide crystals are studied.
综述了酰基叠氮化合物在有机合成中的应用。
Its applications as an organic intermediate in organic synthesis are reviewed.
介绍了由醛、 酰肼、 羧酸、酰氯、酐或酯合成酰基叠氮化合物方法。
Synthesis of acyl azide from aldehyde, or acylhydrazine, or carboxylic acid , or acyl chloride, or anhydride, or ester is introduced in this paper.
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