叔醇(Tertiary alcohol)是羟基所在位置有三个取代基的醇,即R1-C(R2)(R3)-OH(没有α-H的醇),醇羟基不能被氧化,而叔醇可以与氧气发生氧化反应。
本文采用酰化法和DCC法合成了一系列叔醇酯。
A series of esters of tertiary alcohols have been effectively synthesized by acylation and the DCC methods.
由橙花叔醇、香叶基衍生物和其它多种原料经不同的化学反应手段,可以合成金合欢醇。
Farnesol can be synthesized by different chemical means from different materials, such as, nerolidol, geranyl derivatives or other (compounds).
结果表明, 经氯化汞活化的金属钐对酮类化合物与烯丙基或苄基卤代物的反应很有效, 可高产率地生成叔醇。
Samarium metal (activated by HgCl2) is an effective reagent for allylation or benzylation of ketones. The corresponding tertiary alcs. are obtained in satisfactory yields.
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