The rate constants are deduced using canonical variational transition-state theory(CVT)with small curvature tunneling corrections(SCT)over a wide temperature range 400～1200 K. The reaction rate expressions are K_H(T)= k(T)=(2.22×10~(-12))exp(-2011.15/T),K_(Cl)(T)=4.46×10~(-11)exp(-68.95/T),K_(OH)(T)= 1.97×10~(-12)exp(-1609.66/T)and k_(O(~3P))(T)=7.48×10~(-14)exp(-544.34/T),respectively.3.
使用小曲率隧道效应校正的变分过渡态理论研究了这些反应在400～1200 K范围内的反应动力学特性。 反应速率常数分别为k_H(T)=(2.22×10~(-12))exp(-2011.15/T)、k_(Cl)(T)=4.46×10~(-11)exp(-68.95/T)、k_(OH)(T)=1.97×10~(-12)exp(-1609.66/T)、k_O(~3p)(T)=7.48×10~(-14)exp(-544.34/T)。
参考来源 - 二噁英形成及降解过程中重要反应的理论研究·2,447,543篇论文数据，部分数据来源于NoteExpress
The theoretical rate constants in the conventional transition state theory and the variational transition state theory with correction of tunneling effect were calculated.
用传统过渡态理论和变分过渡态理论及相关的隧道效应校正计算了反应的速率常数。
The reaction rate constants have been calculated according to conventional transition state theory, variational transition state theory and tunneling corrections respectively.
根据传统过渡态理论、变分过渡态理论及相应的隧道效应校正，计算了本重排反应的反应速率常数。
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