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Substitute Gonzalo Higuain added a third after coming on as substitute to all but seal his side's place in the last four with 17 minutes remaining.
CNN: Mourinho on course for date with destiny
Jimmy Floyd Hasselbaink came off the bench to score Boro's third goal before fellow substitute Massimo Maccarone netted the winner at the death.
BBC: Massimo Maccarone's late goal sparked wild celebrations
Mirko Vucinic added a third six minutes later before substitute Alessandro Matri completed the rout with ten minutes remaining.
CNN: Ten-man Barcelona shocked by Sociedad
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