And what that says is that the heat capacity and of course we could take the limit of this, but we can just take the derivative of this with respect to temperature more easily.
那意味着热容,当然我们也可以做它的极限,但我们用它,对温度求导更容易些。
So let's take the derivative with respect to the temperature on the bottom first.
让我们首先,对分母做温度的微分。
OK, now I have this derivative of the Gibbs free energy divided by the temperature.
现在要进行微分,对除以温度之后的吉布斯自由能。
Then we can take the derivative of that quantity, when we vary the temperature, holding the volume constant.
即恒定体积,改变温度,这里恒定温度下。
And then we can take the derivative with respect to temperature, it's just R over molar volume minus b.
这样我们求,压强对温度的偏导数,结果等于R除以摩尔体积V杠减去b的差。
du/dT constant pressure is the direct derivative with respect to temperature here, which is sitting by itself under constant volume keeping this constant but there is temperature sitting right here too.
偏U偏T,p恒定是对,温度的直接微分,而它本身对体积不变,保持它不变,但是这里也有一个温度,这就是偏U偏V,T恒定。
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