The result of kinetic analysis showed that the depolymerization reaction was first order to the polycarbonate concentration in supercritical and sub-critical water and water/methanol mixture. The activation energy was 99.77 kJ·mol~(-1)in supercritical and sub-critical water and 91.45 kJ·mol~(-1)in water/methanol mixture.
根据实验数据得出聚碳酸酯在超/亚临界水及水/甲醇混合流体中的解聚反应为一级反应,通过关联实验数据,得到超亚临界水中PC的解聚反应活化能为99.77kJ·mol~(-1),混合流体中PC的解聚反应活化能为91.45kJ·mol~(-1)。
参考来源 - 超亚临界水、甲醇、水/甲醇混合流体中聚碳酸酯解聚研究·2,447,543篇论文数据，部分数据来源于NoteExpress
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