The first part describes the syntheses of natural products by means of diastereoselective propargylation.
第一部分描述了通过非对映选择性炔丙基化合成天然产物。
The first part describes the syntheses of natural products and natural-like products by means of diastereoselective propargylation as the key step.
第一部分是以基于锌粉-溴丙炔体系的、非对映选择性的炔丙基化反应为关键步骤,合成天然及类天然产物。
Among the existing means to construct these synthetically and biologically important molecules, metal-mediated allylation and propargylation is one of the easiest and most convenient.
在现存的用来构建这些重要的合成子和生物分子的方法中,金属促进的羰基化合物烯丙基化和炔丙基化是最容易和最方便的。
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