Prato reaction
- 普拉托反应（普拉托反应是一种在富勒烯或碳纳米管与亚甲胺鎓内盐之间的1,3-偶极环加成反应，可制取官能化富勒烯/（单壁）纳米管，是对富勒烯进行表面化学修饰的重要方法之一。此反应可逆，可通过环消除再生C60。在胺上带有芳基时，反应前，该芳基可在纳米管表面进行自组装，从而使该反应在室温下就可进行）
Prato reaction
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abstract:
The Prato reaction in fullerene chemistry describes the functionalization of fullerenes and nanotubes with azomethine ylides in a 1,3-dipolar cycloaddition. The amino acid sarcosine reacts with paraformaldehyde when heated at reflux in toluene to an ylide which reacts with a double in a 6,6 ring position in a fullerene in a 1,3-dipolar cycloaddition to yield a N-methylpyrrolidine derivative or pyrrolidinofullerene or pyrrolidino3,4:1,2 [60]fullerene in 82% yield.
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