Second,azobenzene groups were introduced to the side chain of poly(2-(dimethylamino) ethyl methacrylate-co-azidopropyl methacrylate),P(DMA-co-AzPMA),by using the click chemistry technology. By mixing aqueous solutions of azobenzene polymer and oligo-β-cyclodextrin,multi-responsive physical hydrogel can form due to the inclusion complexation.
接着合成了侧链被偶氮苯基团部分改性的聚N,N-二甲基氨乙基甲基丙烯酸酯(PDMA-co-PAzoC6PMA),并利用偶氮苯基团和环糊精之间的包结络合作用和低聚环糊精(oligo-(β-CD))在水溶液中混合构筑超分子水凝胶。
参考来源 - 环境响应性超分子聚集体的制备及组装过程研究·2,447,543篇论文数据,部分数据来源于NoteExpress
The supramolecular system stoichiometry is 1:1 for all amino acid inclusion complexation with host compounds (1) and (3).
化学计量法表明,所有的氨基酸均与环糊精衍生物形成了1:1的超分子体系。
Therefore, properly high column temperature can balance between high column efficiency and high selectivity via partial inclusion complexation and portal synergetic interactions.
适当的高柱温既保留了部分包结作用,同时存在端口协同作用,能兼顾高选择性和高柱效。
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