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If it's a reversible process then the equality holds, but if it's irreversible, which means it happens spontaneously, t then ds is greater than this.
对于可逆过程,等号成立,但是如果是不可逆过程,这些不可逆过程是自发进行的,那么dS大于dq除以。
We saw that in general dS is greater than T or equal to dq over T.
我们发现一般来说dS大于,或者等于dq除以。
So then, just like we saw, analogous to what saw just before, dS/dp it's T dS/dp at constant T.
就像我们看到的,就像我们刚才看到的一样,结果是T乘以恒定温度下的。
SdT This has minus T dS minus S dT, but the dT part is zero because we're at constant temperature.
这一项包含负的Tds和,但是dT的部分等于零,因为温度为常数。
TdS It comes from the fact that dq reversible is T dS, pdV and dw reversible is minus p dV.
这个结论来自于:可逆过程下dq等于,做功dw等负的。
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