The results of TPD and TPSR indicated that CO occupied the active sites, thus suppressed the reverse water-gas reaction of CO2 and enhanced the formation of methanol.
TPD和TPSR结果表明,CO占据催化剂表面部分活性位并抑制CO2的逆水煤气转换,促进了甲醇的生成。
TPD MSand TPSR MS results indicate that COcan suppress the adsorption of CO2 on the sites, which bring about the reverse water gas shift reaction and hence promote the selectivity of methanol.
TPD-MS和TPSR-MS结果表明,CO能抑制催化剂表面起逆水汽变换作用的活性位对CO2的吸附,从而提高了CO2加氢合成甲醇的选抒性。
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