Ola Toivonen earlier had a goal harshly ruled out for offside and Tobias Hysen was denied late on by substitute keeper Wayne Hennessey.

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Defender Adil Rami put Valencia ahead early on in the second half, before Ola Toivonen made it all-square on the night in the 64th minute.

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Alexander had his hands on the ball early on as he collected a couple of PSV crosses but his first real save came in the 16th minute when he raced off his line to gather at the feet of Berg, who had run on to Ola Toivonen's incisive pass.

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