Oxidative carbonylation of methanol to dimethyl carbonate catalyzed by a series of copper complexes bearing ligands with nitrogen, oxygen and phosphine donors is reported.
报道了一系列铜与含氮、氧、磷配体形成的配位催化剂用于甲醇氧化羰化合成碳酸二甲酯的研究结果。
Compare to the traditional phosgene process, synthesis of DMC by oxidative carbonylation of methanol is more favorable because of its simple, environmental benign and cost-effective characters.
甲醇氧化羰化羰化法是合成dmc的一种新工艺路线，该工艺与传统的光气法工艺相比，具有工艺流程简单、无三废污染及生产成本低等优点。
Synthesis process of dimethyl carbonate is reviewed. Oxidative carbonylation of methanol to DMC and the possibilities of replacement of DMS and COCl_2 by DMC are discussed.
讨论了碳酸二甲酯的合成工艺，主要介绍氧化羰基合成工艺，并对碳酸二甲酯取代硫酸二甲酯和光气市场的可能性进行了分析。
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