The effect of the electron-donating groups on the electronic spectrum was investigated.
探讨了给电子基团对电子吸收光谱的影响。
It was found that introducing electron donating groups, such as alkyls, weaken the electron accepting ability of C60 and make its first reduction wave shifted to more negative position.
结果发现,引入推电子基团,如烷基,会使C60得电子能力降低,第一个还原电位有较大的负移;
The groups in ring of benzaldehydes, no matter they are electron withdrowing or electron donating except of hydroxy, do not seem to have much effect on the yield.
羟基处于醛基邻位和对位的苯甲醛与几种苯乙酮衍生物的缩合,多数没有得到预期的产物,或收率极低;苯乙酮环上的羟基对缩合反应影响很大,羟基越多,缩合越困难。
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