...类[1]:采用高比表面积活性炭的电容器的储能机理是基于碳电极/电解液界面上电荷分离所产生的双电层电容(double layer capacitance);采用RuO2等贵金属氧化物或PPy等导电高分子聚合物作电极的电容器是在氧化物电极表面或在内部的二维或准二维空
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But, the effect of diffusible double-layer on double layer capacitance is re-duced and even eliminated through increasing pore sizes of carbon electrodes or electrolyte concentration.
而增大炭材料的孔径或电解液浓度,可明显减弱甚至消除扩散层对电容的影响。
The large capacitance exhibited by these systems was demonstrated to arise from a combination of the double-layer capacitance and pseudo-capacitance associated with surface redox-type reactions.
研究证明,电化学电容所具有的大容量是由于电极表面的双电层电容和氧化还原反应导致的“准电容”的共同作用而引起的。
Hydration of ion has bad influences on double-layer capacitance of carbon electrode, which can be reduced effectively by selecting large ion or increasing pore size of carbon electrode.
离子水化对炭电极的电容产生不利影响,选用大离子和增大炭材料的孔径,可有效降低离子水化对炭电极电容性能的影响。
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