Currently, the reaction progress monitoring focuses on amide acylation and deprotection reaction, while there is no method for the reaction progress of the intermediate-active esters.
目前,合成过程的中间监测方法主要集中在胺酰化及脱保护反应,而对于中间体一活化酯的反应进程没有监测方法。
Chiral ketone 4 derived from D-(-)-fructose was obtained by four steps reaction including protection with acetone, oxidation, deprotection selectively and trifluroacetylation.
以D-(-)-果糖为手性源,经过丙酮保护、氧化、选择性脱保护、三氟酰化四步反应得到手性酮4。
The photoinduced electron transfer reaction between N-tosyl amides and 2-phenyl-N, N'-dimethyl benzimidazoline (PDMBI) provides an efficient approach for the deprotection of N-tosyl amides.
对甲苯磺酰基酰胺和2-苯基-N,N'-二甲基苯并咪唑啉(PDMBI)之间的光诱导电子转移反应,为酰胺的保护基——对甲苯磺酰基的脱除反应,提供了一条有效途径。
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