计算结果显示1的两个低能三重激发态分别产生399和234nm发射,属于金属中心(Metal-centered,MC)跃迁和分子内电荷转移(Intramolecular Charge Transfer,ICT)的混合性...
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金属中心为六配位略微变形的八面体几何构型。
The central metals was six-coordinated with octahedron geometry.
介绍了用紫外光谱研究配合物金属中心结构的原理。
The principle of UV spectroscopy applied in structural studies of metal centre of complexes is introduced in this paper.
酸量过小的催化剂抗硫性差则与金属中心缺电子效应较小有关。
The low sulfur tolerance of the catalyst with a low acid amount was attributed to the insignificance of the electron deficiency of the metal particles.
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