化学修饰实验发现：巯基、胍基、氨基、羧基和吲哚基可能参与酶活性中心的组成。

Chemical modification studies showed that the sulfhydryl, guanido, amino, carboxyl and indolyl groups may participate in the active center of the enzyme.

youdao

本论文主要合成了一系列唯铁氢化酶活性中心六羰基二铁二硫模型配合物并考察其结构特性。

Herein, a series of diiron dithiolate complexes were synthesized as the structural and functional models of the Fe-only hydrogenase active site.

youdao

为研究氢化酶活性中心氮桥结构中氮原子是否起到质子摆渡的作用，设计了在分子内引入氢键的结构。

To explore the role of the bridged N atom for a possible proton transfer in the active site of hydrogenase, we tried to introduce a hydrogen bond into a couple of designed molecules.

youdao