本体聚合法是单体在引发剂或热、光、辐射的作用下,不加其他介质进行的聚合过程。特点是产品纯洁,不需复杂的分离、提纯,操作较简单,生产设备利用率高。可以直接生产管材、板材等制品,故又称块状聚合。缺点是物料粘度随着聚和反应的进行而不断增加,混合和传热困难,反应器温度不易控制。
以金属配合物为催化剂、1,5 -己二烯为交联剂,采用本体聚合法合成了交联超高相对分子质量烯烃类聚合物(简称交联聚合物)。
Ultra high relative molecular mass cross-linked alkene polymer was synthesized by bulk polymerization using metal complex as catalyst and 1, 5-hexadiene as cross-linking agent.
采用本体聚合方法将丙烯酸酯单体的混合物实施热聚合制备预聚体,采用核-壳聚合法的单体投料方式同时加入链转移剂十二烷基硫酵来控制反应进程。
UV curing polyacrylate pressure sensitive adhesive was synthesized by core-shell polymerization, at the same time, chain transfer agent NDM was added for controlled reaction rate.
采用本体熔融聚合法制备了可紫外光固化的不饱和聚酯酰胺脲树脂,该类树脂可用作紫外光固化涂料,并对树脂进行了红外表征。
UV-curable unsaturated polyester-urea resins which could be used as UV-curing coating were prepared by melting method and its structure was determined by FT-IR.
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