...报(自然科学版、英文版) 关键字: 手性离子液体;配体交换拆分;热力学;邻氯扁桃酸[gap=1080]Key words: chiral ionic liquids; ligand exchange enantioseparation; thermodynamics; 2-chloromandelic acid..
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但对于手性离子液体 chiral ionic liquid
With optimized conditions, we then applied synthesized chiral ionic liquids and ionic salts having different the anion and cation to this reaction. According to the results, the possible cause has been given after the study.
在此优化条件下,研究了几种具有不同阴阳离子结构的手性离子液体和离子盐在此反应中的影响,并对产生的影响作了相关的解释说明。
参考来源 - 手性离子液体的制备及其对乙酰乙酸甲酯不对称加氢反应的影响·2,447,543篇论文数据,部分数据来源于NoteExpress
手性离子液体可以作为手性溶剂,催化剂载体或手性诱导剂,应用于手性合成、手性分离和手性催化等领域。
Chiral ionic liquids are used as chiral solvents, catalyst carrier or chiral inducer in chiral synthesis, chiral separation, chiral catalysis and other fields.
重点介绍了目前主要的功能化和手性咪唑离子液体合成方法。
Highlighted the main features of the present and the synthesis of functional and chiral imidazole ionic liquid method.
另外,在离子液体中,水含量的增加在一定程度上可以增大酯化手性选择性,但反应速率会被降低。
Moreover, higher water content in the ionic liquid was favorable for obtaining higher enantioselectivity, however it lowered the reaction rate and(DL)-menthol conversion.
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