手性二胺的合成及其在催化不对称反应中的应用_stmopen 关键词】: 手性二胺 合成 催化不对称反应 应用 [gap=479]Keywords】: chiral diamine,synthesis,catalytic asymmetric reaction,application
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通过烯丙基溴化锌对手性亚胺的两次不对称加成,合成了光活性的双烯丙基化的新型手性二胺。
A novel chiral diallylic diamine has been synthesized through double addition of allyl zinc bromide to chiral imines in this contribution.
通过将手性胺和酸基团同时引入到二氧化硅表面制备得到了一种多相双功能催化剂。
A heterogeneous bifunctional catalyst was synthesized by incorporating chiral amine and acid groups into silica.
综述了手性1,2 二苯基1,2 乙二胺及其衍生物的合成,以及作为手性辅助基和手性配体在不对称合成中的应用。
This review summarizes the synthesis and the application of 1,2-diphenyl- 1,2-diaminoethane and its derivatives as chiral auxiliaries, chiral ligands and chiral reagents in asymmetric synthesis.
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