探讨碱性、溶剂极性、离去基团、吸电子基团、亲核试剂的亲核性对反应影响。
There are impact factor to be discussed such as solvent polarity, nucleofuge, attract electron group the nunucleophilicity of nucleophilic reagent.
含活性基团的醛可与烯丙基碘和锡粉直接进行亲核加成反应,得到高烯丙基型的醇。水的存在不利于此反应的进行。
Aldehyde containing functional groups can react with allyl iodine and tin directly, water is of no advantage to the reaction.
并且对亲核试剂的体积效应、溶剂效应对亲核性影响,底物上吸电子基团的数目、吸电子能力对亲电性的影响,以及亲核取代反应的发生部位受哪些因素影响进行探讨。
At the same time, discuss about the impact factor to nucleophilicity such as the number of attract electron group, ability of attract electron and the nucleophilic substitution reaction part.
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