酵母发酵液催化不对称还原反应合成(S)-药学论文-论文联盟 Keywords】 yeast fermentation broth; asymmetric reduction; ethyl 4chloro3oxobutanoate; (S)ethyl 4Chloro3hydroxybutanoate; orthogonal text[gap=406]关键词】 酵母发酵液；不对称还原反...
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不对称诱导的还原反应 Asymmetrical induced reduction
本文综述了应用手性高分子试剂和催化剂对潜手性化合物通过不对称氧化、还原、烷基化、加成反应进行不对称合成的进展情况。
This review deals with the recent progress in asymmetric synthesis using chiral polymeric reagents and catalysts for oxidation, reduction, alkylation and addition of prochiral compounds.
按反应类型分类，综述了酮的不对称还原方法及其近年来的新进展。
In this review, asymmetric reduction of prochiral ketones and its recent advances have been described according to the reaction types.
生物催化的还原反应能使分子内的羰基或碳-碳双键立体选择性的还原，将潜手性底物转化为手性产物，在不对称合成中有着重要的作用。
Biocatalytic reduction of the carbonyl groups or the carbon-carbon double bonds of the compounds has been utilized as a method for transforming the prochiral substrate into chiral product.
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