以羟基作为聚醚链端基的的催化活性最高, 在相同条件下, 其表观一级速率常数约为的3倍, 为的30倍。
Under the same condition, the pseudo-first-order rate constant kobs (s-1) of BNPP hydrolysis catalyzed by is about 3 times that of , and about 30 times that of , respectively.
吸附动力学过程包括吸附快反应阶段和慢反应阶段,可用动力学一级方程和双常数速率方程描述;
The sorption kinetics included the initial fast phase and the final slow phase. The first-order kinetic reaction and double constant rate equation could describe the sorption kinetics well.
假定它们为一级反应,推导出各组份的反应动力学方程序,并求得各反应的反应速率常数及表观活化能。
Assuming that all of them were of first order reaction, the rate equations for each reaction were derived and rate constants and the apparent activation energies of them were calculated.
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