Whereas under these conditions, these quantities, if you look at free energy change, for example at constant temperature and pressure, H you can still calculate H.
但是,在这些条件下,这些物理量,如果我们考察自由能的变化,例如在恒定的温度和压强下,我们仍然可以计算。
It's a state function, so we're at constant temperature and pressure, and now we want to consider some chemical change or a phase transition or you name it.
这就是态函数,我们处于恒定的温度和压强之下,然后考虑某些化学变化或者相变,或者你想考虑的东西。
Dealing with constant change and pressure is part of the answer.
应对复杂多变的情况和压力可能是部分原因。
Whereas under these conditions, these quantities, if you look at free energy change, for example at constant temperature and pressure, H you can still calculate H.
但是,在这些条件下,这些物理量,如果我们考察自由能的变化,例如在恒定的温度和压强下,我们仍然可以计算。
It's a state function, so we're at constant temperature and pressure, and now we want to consider some chemical change or a phase transition or you name it.
这就是态函数,我们处于恒定的温度和压强之下,然后考虑某些化学变化或者相变,或者你想考虑的东西。
You just change volume to pressure and basically you're looking at enthalpy under a constant -- anything that's done at a constant volume path with energy, there's the same thing happening under constant pressure path for enthalpy.
可以看到这就是把体积换成了压强,一般我们都是在一种恒定状态下,考虑焓的,任何在恒容条件下,能伴随能量变化的东西,也在恒压条件下伴随焓同样地变化,所以你可以经常。
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