2-Alkyl-4,4,4-trichloro-2-butenals was obtained via dehydration of the aldol products prepared through direct cross-aldol reactions of chloral with aliphatic aldehydes at first. The asymmetric bioreduction of thisα,β- unsaturated aldehyde was next studied in detail.
首先通过三氯乙醛与丙醛、正丁醛的交叉缩合反应合成了羟醛缩合产物,然后将其脱水得到2-烷基-4,4,4-三氯-2-丁烯醛,之后对这种α,β-不饱和醛的面包酵母催化不对称还原反应进行了系统的研究。
参考来源 - 面包酵母催化还原2·2,447,543篇论文数据,部分数据来源于NoteExpress
N a colourless oily liquid with a pungent odour, made from chlorine and acetaldehyde and used in preparing chloral hydrate and DDT; trichloroacetaldehyde 三氯乙醛
No, Chloral Hydrate has a half-life of only 4 hours in people with a high tolerance.
不是,对“水合三氯乙醛”有较高耐药能力的人,它的半衰期仅为4个小时。
The purpose of the preparation of chloral hydrate suppository and its quality control methods.
目的制备水合氯醛栓剂,并探讨其质量控制方法。
Results: it was found that all of these factors had influence on the stability of chloral hydrate.
结果:发现这些因素均影响水合氯醛的稳定性,其中以紫外线照射及碱性物质影响最大。
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