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Timmy Simons' drive was comfortably beaten away by Diego Cavalieri as the hosts finally got a shot in on goal.
BBC: PSV 1-3 Liverpool
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They have already drafted in Philipp Degen, fellow full-back Andrea Dossena, goalkeeper Diego Cavalieri and teenagers David Ngog and Emmanuel Mendy.
BBC: Liverpool complete Keane transfer
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Cavalieri will be the reserve keeper as Jose Reina maintains the starting spot and it seems likely that England international Scott Carson will also be leaving Anfield.
CNN: Goalkeeper Cavalieri on way to Liverpool