【Key words】 Pd nanowire electrode; electrocatalytic oxidation; methanol; alkaline media
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In alkaline medium, bicarbonate reacts with hydrogen peroxide to form peroxymonocarbonate ion (HCO4-), which is an unstable compound. During the decomposition of HCO4-, a weak CL was observed.
在碱性介质中,碳酸氢盐与过氧化氢在线反应生成过氧碳酸盐(HCO4-), HCO4-不稳定分解可以产生微弱的化学发光。
参考来源 - 纳米粒子增强碳酸氢盐—过氧化氢化学发光反应过程研究And in alkaline media heterogeneous electrocatalytic synthetic mechanism was investigated on Nanocrystalline TiO2 Electrode. Under optimum conditions the yield and current efficiency of synthetic p-Aminobenzoic acid can reach 96.7% and 92.8% respectively, with product purity being 99.4%.
运用电化学方法研究了Ti/nano-TiO2膜电极还原对硝基苯甲酸为对氨基苯甲酸的电催化还原活性和选择性；探讨了在碱性介质中，纳米TiO2膜修饰电极异相电催化还原对硝基苯甲酸为对氨基苯甲酸的机理，合成的对氨基苯甲酸的产率达96.7 %，产物纯度为99.4 %，电流效率为92.8 %。
参考来源 - 纳米TiO·2,447,543篇论文数据，部分数据来源于NoteExpress
结果表明：碱性介质中异丙醇电氧化过程不存在自毒化现象。
The results show that there is no self-poisoning in the electrooxidation of isopropanol in alkaline media.
在强碱性介质中，“固体表面活度”很低，若二硫代碳酸盐浓度不大，则不能发生吸附。
In serious alkaline media, "solid surface activity" values are quite low and the adsorption can't take place therefore.
采用高压釜实验，研究烟煤在碱性介质中氧气氧化时加入有机脂肪酸促进剂对产品生成的影响。
This investigation is about the influence of fatty acid used as the promoter on the product of bituminous coal oxidation by oxygen and alkaline solution acting in an autoclave.
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