把亲核剂的亲核性和碱性的区别与相同之处进行了比较。
It compares the nucleophilicity of nocleophilic reagent with the similarities and differences of basicity.
探讨碱性、溶剂极性、离去基团、吸电子基团、亲核试剂的亲核性对反应影响。
There are impact factor to be discussed such as solvent polarity, nucleofuge, attract electron group the nunucleophilicity of nucleophilic reagent.
在B3LYP/ 6-311G计算所得的平衡几何构型基础上,分别根据静电势和分子轨道计算研究了分子中-NH2和-N(CH3)2的亲核性,并与偏二甲基肼和卤代烃反应的实验结果进行了对比分析。
On the basis of equilibrated geometrical structure obtained by B3LYP/6-311G method, the nucleophilicity of-N(CH3)2 and-NH2 groups are investigated by electrostatic potential and MO calculations.
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