在讨论热力学第三定律的时候,我们讨论过压强变化,即对于纯净的完美晶体,随着温度下降到绝对零度熵也变成零。
We looked at pressure change before, actually, in discussing the third law, the fact that the entropy goes to zero as the absolute temperature goes to zero for a pure, perfect crystal.
对零点剩余炳的存在提出了一种新解释,指出零点剩余熵的存在和熵冻结实际上是等价的,比热测量的结果并不违背热力学第三定律。
It is shown that the existence of the residual entropy and the entropy-freezing are in fact equal and that the third law of thermodynamics is still valid in glass systems.
介绍了证明热力学第三定律的一种简单方法并给出了其统计解释。
A simple method is introduced to prove the third law of thermodynamics and the statistical exposition has been given for it.
And the bigger lesson from that is that entropy, unlike energy u or enthalpy H, we could define an absolutely number for it.
热力学第三定律的一个更重要的推论是,与内能和自由焓不同,我们可以给上定义一个绝对的数值。
We looked at pressure change before, actually, in discussing the third law, the fact that the entropy goes to zero as the absolute temperature goes to zero for a pure,perfect crystal.
在讨论热力学第三定律的时候,我们讨论过压强变化,即对于纯净的完美晶体,随着温度下降到绝对零度熵也变成零。
So, over the last few lectures we've worked and struggled so formulate the second and third laws of thermodynamics in addition to the first.
在前几次课中,我们通过努力明确的,给出了热力学,第一,第二和第三定律。
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