通过对自由基反应原理和引发剂活性的阐述,结合高压聚乙烯管式法工艺,分析有机过氧化物引发剂在高压聚乙烯的选择应用。
The selection and application of organic peroxides initiators in LDPE production are discussed. The reaction of free radical and activity of the initiator are also described.
一般说来,引发剂的卤化物组份的活性,是随连在同一碳原子上的氯和溴原子的数目的增多而增长。
In general, the activity of the halide component of the initiator increases with the number of chlorine or bromine atoms joined to a single carbon atom.
引发剂用量增加使得体系中活性中心浓度增加因此共聚物的产率上升;
The concentration of active center increases with the increase of dosage of initiator, so the yield of copolymer increase.
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