文摘:综述了近几年钌亚乙烯基络合物中间体-碳的亲核反应。亲核试剂包括烯烃、炔烃、 醇、酸、胺、水等。
Abstract : this article reviews recent progress in nucleophilic reactions of the - carbon in vinylidene ruthenium complexes. the nucleophiles include alkene, alkyne, alcohol, acid, amine, water, etc.
用硫酸乙酐混合物作环合剂,制备了氟嗪酸中间体.该方法具有反应条件温和、价格便宜、后处理简单的优点,适用于工业化生产。
Sulfuric acid and acetic anhydride were used as a cyclizing agent to prepare Ofloxacin intermediate. The reaction could be carried out under moderate conditions and facilitate industrial produce.
重点叙述了某些光学活性中间体的工业合成技术,包括手性氨基酸、手性羧酸、手性醇、手性胺和手性环氧化物。
The industrial synthesis of certain optically active intermediates, including chiral amino acids, carboxylic acids, alcohols, amines and epoxides is reviewed.
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