• 两个中间产物可以作为羰基还原选择性还原,但具有不同反应速率

    They could be used as the substrates for the reduction catalyzed by diketoreductase with different reaction velocities.

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  • 结果两个羟基中间产物产生羰基还原及其逆反应过程中分离纯化鉴定。

    Results: Two mono-hydroxy intermediates were produced during the diketone reduction process and its reverse reaction, which were separated and structurally confirmed.

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  • 概述了低价诱导羰基还原偶合反应作为环化关键步骤西松二萜天然产物合成中的应用

    The application of carbonyl reductive coupling reaction induced by low valent titanium as the crucial macrocyclization in the total syntheses of cembrane- type diterpenoids are reviewed.

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  • 化合物还原红曲色素,红斑素红曲红素分子中的环羰基还原羟基,得到水溶性红白曲黄色素。

    The water soluble Monascus yellow pigment was prepared by reducing the cyclocarbonyl of monascorubrin and rubropunctatin to hydroxyl with sulphuric compounds.

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  • 这些就是所谓的还原意味着它们——“有趣尾巴Corriher女士这样形容——羰基基团可以参与Maillard反应

    These are so-called reducing sugars, which means they have a structure - "a funny tail," Ms. Corriher called it - known as a carbonyl group that takes part in the Maillard reaction.

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  • 羰基在一般条件下不易被化学还原还原

    The chemical reductants fail to reduce carbonyl group under ambient conditions.

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  • 结合生物催化优势利用微生物细胞催化不对称还原羰基化合物可以有效制备这些手性

    Combining the advantages of biocatalysis in nonaqueous media, asymmetric reduction of corresponding carbonyl compounds using microbial cells is an efficient method to produce these chiral alcohols.

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  • 此外,它除了还原双键以外可以用来还原各种不同有机化合物硝基羰基氨基芳香族杂环化合物羟基羧基

    Moreover, catalytic hydrogenation can be used to the reduction of a variety of organic compounds, such as nitro, carbonyl, amino, aromatic and heteroaromatic compound, hydroxy group and carboxy group.

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  • 生物催化还原反应能使分子内羰基-碳双键立体选择性的还原,将底物转化手性产物,在不对称合成中有着重要的作用。

    Biocatalytic reduction of the carbonyl groups or the carbon-carbon double bonds of the compounds has been utilized as a method for transforming the prochiral substrate into chiral product.

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  • 药物合成重要手性砌块利用生物催化剂不对称还原羰基化合物手性醇制备重要方法。

    Chiral alcohols are important building blocks for drug synthesis. The asymmetric reduction of carbonyl compounds with biocatalysts is an important method for producing chiral alcohols.

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  • 本文概述硝基选择氧化还原羰基化生成工艺路线。

    A new process for the synthesis of ureas based on the selective REDOX carbonylation of amine and nitro compounds was described.

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  • 羰基化合物还原偶合形成碳-碳一种重要方法

    The reductive coupling of carbonyl compounds constitutes an important method for the formation of carbon-carbon bonds.

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  • 羰基化合物还原偶合形成碳-碳一种重要方法

    The reductive coupling of carbonyl compounds constitutes an important method for the formation of carbon-carbon bonds.

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