从氯化苄和异丁醛经相转移反应及催化加氢的方法得铃兰醇。
Benzyl chloride and isobutylaldehyde were transformed into muguet alcohol through phase-transfer reaction and catalytic hydrogenation.
结果表明,升高反应温度、以丙酮为共溶剂或以十二烷基硫酸钠作相转移剂均可使反应速度加快。
The results show that increasing reaction temperature, using acetone as cosolvent or sodium dodecyl sulfate as phase-transfer reagent can accelerate the reaction.
相转移法合成萘丁美酮具有所用试剂易得,操作方法简便,反应条件温和,成本较低等优点。
CONCLUSION The phase transfer catalyst has advantages of simple starting material, convenient operations and mild reaction conditions.
表面活性剂催化化学反应过程的机理有胶束催化和相转移催化。
These catalytic mechanisms of interfacial agent in some chemical reactions are micelle catalysis and phase transfer catalysis.
在此新反应体系中,催化剂呈现反应过程相转移催化特性,产物易分离,催化剂可回收循环利用。
In the new reaction system, product can easily isolate and catalyst can be recycled owing to the phase transfer catalysis character of catalyst in reaction process.
在相转移催化反应体系中,超声能够取代相转移催化剂,使反应顺利进行。
Ultrasound may replace phase transfer catalysts in phase transfer catalysis reactions and facilitate the reaction.
对反应合成、相转移催化机理和合成工艺进行了研究和实验探索,经条件优化实验确定了较佳的合成工艺参数。
The mechanism of the reaction and that of phase transfer catalysis were studied. The process parameters were selected by optimum experiment.
测定了其对氧烷基化反应、氮烷基化反应的相转移催化作用。
Their phase transfer catalytic ability for the reaction of N-alkylation, O-alkylation and oxidation were also determined.
利用相转移催化法合成香料2-甲基-3 甲氧基吡嗪,并对其反应条件进行探讨,找到较佳的反应条件。
The synthetic method of perfume 2 - methyl - 3 - methoxy pyrazine was investigated and better reaction conditions have been found.
由于相转移催化具有反应条件温和、反应速度快、反应收率高等优点,使其成为研究的热点。
Phase transfer catalysis is hot point now because of its merit of temperate react condition, quick react rate and high production yield.
本文报道了二苯基烯丙基型鏻盐与取代芳醛在碳酸钾作用下的固一液相转移催化反应。
The phase transfer catalyzed Wittig reaction of allyl diphenyl phosphonium salt with substituted aromatic aldehydes using potassium carbonate as base provides 1, 3-dienes with good E-selectivity.
磷钨杂多酸季铵盐作为相转移催化剂,在胶束两相催化反应中具有良好催化效率。
Quaternary ammonium heteropolyphosphatotungstate, as one kind of the phase transfer catalysts, has good catalysis activity in two phase catalysis reaction of micelle.
相转移催化环烷基化反应不适合采用无溶剂法来进行,对反应过程中的溶剂效应进行分析后选择甲苯作为溶剂和带水剂。
The reaction was not suitable conducted under solvent-free condition, water formed during the reaction was removed by azeotropic distillation with toluene throughout the reaction.
实验结果表明,反应温度和溴代正丁烷的用量是相转移催化合成噻酮工艺的主要影响因素。
The experimental results indicated that the reaction temperature and the dosage of 1-butyl bromide were the main factors while the reaction time and the dosage of TBAB were the minor factors.
实验结果表明,反应温度和溴代正丁烷的用量是相转移催化合成噻酮工艺的主要影响因素。
The experimental results indicated that the reaction temperature and the dosage of 1-butyl bromide were the main factors while the reaction time and the dosage of TBAB were the minor factors.
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