• 提到生催化,我们通常会想到旋物动力学拆分手性合成

    When considering biocatalysis, terms like kinetic racemic resolution or chiral syntheses immediately come to mind.

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  • 消旋动力学拆分反应制备手性化合重要方法之一

    The kinetic resolution of raceme is one of the important ways in the synthesis of chiral compounds.

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  • 固体消旋蛋氨酸(DLM)蛋氨酸羟基类似自由(MHA - FA)两种常用的蛋氨酸添加剂

    Solid racemated methionine (DLM) and methionine hydroxy analogue free acid (MHA-FA) are two usual methionine additives.

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  • 利用消旋体进行化学-酶催化动态动力学拆分制备单一手性化合有效手段之一

    The chemoenzymatic dynamic kinetic resolution(DKR) of racemates is one of the efficient ways in the preparation of single chiral compounds.

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  • 目前用于拆分外消旋化合多数水解酶,而且绝大多数为脂肪酶

    Presently, most of the catalysts used for the resolution of racemic mixtures are hydrolases, especially lipases.

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  • 综述了手性拆分方法拆分外化合中的应用,讨论了包结拆分中的手性识别原理参考文献47篇。

    The resolution of racemic compounds by crural inclusion complexation reported in 47 references is reviewed with 47 references. The chiral recognition principles in inclusion complex is also discussed.

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  • 理论看,芳香非芳香轮烯是内体和外消旋体的混合,故都呈现性。

    In the light of the helix theory, aromatic annulenes and non-aromatic annulcncs are all the mixture of the mesomer and raceme, so they haven't opticity activeity.

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  • 将所得聚合用作高效液相色谱固定,研究了它们对外卡尼丁盐酸盐拆分能力

    The prepared polymers were applied as the liquid chromatographic chiral stationary phase to test their resolution ability for racemic carnitine hydrochloride.

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  • 消旋体拆分获得单一手性化合重要途径。

    Raceme separation is the main rout for preparation of pure enantiomers.

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  • 聚合作为高效液相色谱固定消旋酮洛固定相能分开同时聚合还能将酮洛芬布洛混合分开。

    Racemic ketoprofen was separated when the polymer was used as a stationary phase of high performance liquid chromatography. The mixture of ketoprofen and ibuprofen were also separated by this polymer.

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  • 有机碱催化剂 ,通过三三甲基丙酮2 ,4-二氯苯甲醛反应合成了具有生活性消旋体化合烯唑醇。

    By using alkalamides as the catalyst, diniconazole has been synthesized by the reaction of triazolyl-trimethylacetone and 2,4-dichlorobenzaldehyde.

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  • 有机碱催化剂 ,通过三三甲基丙酮2 ,4-二氯苯甲醛反应合成了具有生活性消旋体化合烯唑醇。

    By using alkalamides as the catalyst, diniconazole has been synthesized by the reaction of triazolyl-trimethylacetone and 2,4-dichlorobenzaldehyde.

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