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  • 理论优化表明,三个吡啶甲酸分子都具有平面的平衡构型。

    Theoretical optimizations show that the equilibrium geometries of the three picolinic acid molecules are planar.

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  • 但对于不同的构型不需要这样做。

    But the different configurations don't do that.

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  • 所以我们要考虑,所有可能的构型。

    So we have to consider all the possible configurations that we have.

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  • 或许我不应该盖住,把这些构型。

    Maybe I shouldn't have covered up those configurations.

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  • 我们设想的是分子,或聚合物构型。

    And what we're envisioning is molecular or polymer configurations.

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  • 你改变温度,但构型能量没有改变。

    You change the temperature and the configurational energy doesn't change.

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  • 配分函数是什么,这些构型的?

    so what's our molecular partition function for this configurational degree of freedom?

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  • 那么μ,构型的化学势,就是。

    So mu, the chemical potential for these configurations, dA/dN is just dA/dN. With T and V constant.

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  • 于是等于简并度,乘以构型的能量。

    So you can write this as the degeneracy of the configuration, times the energy of the configuration.

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  • 让我们看看一些更复杂的,电子构型。

    So, let's move on to some more complicated electron configurations.

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  • 所以那是一点点关于,电子构型的入门。

    So that's a little bit of an introduction into electron configuration.

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  • 所以所有写构型的地方,都可以写成振动。

    So everywhere where it says configurational, you can just write in vibrational.

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  • 让我们看看这里的,电子构型是什么样的。

    So let's think about what the valence electron configuration is here.

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  • 这是B2的价电子构型。

    So this is our valence electron configuration for b 2.

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  • 聚合物有不同的构型。

    And it has different configurations.

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  • 没有其他的构型能量。

    There's no additional configurational energy.

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  • 在构型配分函数中。

    In the configurational partition function.

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  • 但那是一个实际了解什么是,电子构型的思路。

    But that's an idea of what it actually means to talk about electron configuration.

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  • 对异构型分布数据源的统一访问

    Unified access to distributed heterogeneous data sources

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  • 0广泛合作和架构型数据库的结合。

    "The combination of Web 2.0 mass collaboration with structured databases".

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  • 考虑聚合物的构型。

    So we'll think about polymer configurations.

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  • 这些构型的能量会稍有不同。

    And they might be a little bit different in energy.

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  • 现在我们有我们的大,我们的正则构型配分函数。

    Q And now we have our capital Q, our canonical configurational partition function.

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  • 这一个因为是有限的数目,在这种构型的情况下。

    This one is, because there's a finite number, four in this case, of configurations.

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  • 让我们来画氢原子的,电子构型,分子,氢分子。

    So let's draw the electron configuration of hydrogen, the molecule, molecular hydrogen.

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  • 这就是电子构型。

    So this is our electron configuration.

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  • 解放开发员从而快速的为新程序构型。

    Liberate your developers to rapidly prototype new applications.

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  • 我们看到处理有简单模型,不同构型的聚合物的。

    That is we looked at what would be a simple model for a polymer with different configurations available to it.

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