还讨论了尺寸因子,电负性,选择子的轨道能量等因素对形成焓的影响。
The affection on the enthalpies of formation aroused by factors, such as size factor, electronegativity, the energy of orbit of selectron etc, is also discussed.
其结果显示了配体的质子化和金属配合物的形成受到焓变化的控制。
The result shows that both the protonation of the ligands and the formation of metal complexes are controlled by the change of enthalpy.
聚合物形成共混体系的相容性的预测能够通过聚合物间溶度参数或混合焓变来实现。
The compatibility forecast of polymer blend systems can be performed by the solubility parameter or the mixing enthalpy.
进一步推导出了预测自由表面纳米微粒和镶嵌在高熔点基体中并与基体形成共格界面的非自由表面纳米微粒的熔解熵和熔解焓的计算公式。
Furthermore, we have obtained the relations accounting for the size and shape dependent melting entropy and melting enthalpy of nanoparticles with free and non-free surface.
进一步推导出了预测自由表面纳米微粒和镶嵌在高熔点基体中并与基体形成共格界面的非自由表面纳米微粒的熔解熵和熔解焓的计算公式。
Furthermore, we have obtained the relations accounting for the size and shape dependent melting entropy and melting enthalpy of nanoparticles with free and non-free surface.
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