The behavior of different species during the temperature programmed surface reaction (TPSR) of methane over various catalysts is traced by an on line mass spectrometer.
利用在线质谱分析检测了在各种催化剂上甲烷的程序升温表面反应(TPSR)过程中不同物种的行为。
The varieties and features of surface carbon depositions on nickel catalyst were extensively investigated by TPSR, TPD, XPS and pulse reaction methods.
实验采用TPSR、TPD、XPS和脉冲反应等方法系统研究了镍基催化剂表面积碳的形态和特点。
The results of TPD and TPSR indicated that CO occupied the active sites, thus suppressed the reverse water-gas reaction of CO2 and enhanced the formation of methanol.
TPD和TPSR结果表明,CO占据催化剂表面部分活性位并抑制CO2的逆水煤气转换,促进了甲醇的生成。
The adsorption and dissociation of methane and carbon dioxide for reforming on nickel catalyst were extensively investigated by TPSR, TPD and pulse reaction experiments.
采用TPSR、TPD和脉冲反应等方法对担载型镍基催化剂上甲烷二氧化碳重整反应过程中二者的吸附和解离行为进行了详尽的研究。
TPR and TPSR results confirmed the above conclusion.
TPR和TPSR实验结果证实了上述结论。
TPD MSand TPSR MS results indicate that COcan suppress the adsorption of CO2 on the sites, which bring about the reverse water gas shift reaction and hence promote the selectivity of methanol.
TPD-MS和TPSR-MS结果表明,CO能抑制催化剂表面起逆水汽变换作用的活性位对CO2的吸附,从而提高了CO2加氢合成甲醇的选抒性。
TPD MSand TPSR MS results indicate that COcan suppress the adsorption of CO2 on the sites, which bring about the reverse water gas shift reaction and hence promote the selectivity of methanol.
TPD-MS和TPSR-MS结果表明,CO能抑制催化剂表面起逆水汽变换作用的活性位对CO2的吸附,从而提高了CO2加氢合成甲醇的选抒性。
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